Dimerization of dendrimeric lanthanide complexes: thermodynamic, thermal, and liquid-crystalline properties

…, H Nozary, K Schenk, B Heinrich, B Donnio…

文献索引：Jensen, Thomas Binderup; Terazzi, Emmanuel; Buchwalder, Kerry-Lee; Guenee, Laure; Nozary, Homayoun; Schenk, Kurt; Heinrich, Benoit; Donnio, Bertrand; Guillon, Daniel; Piguet, Claude Inorganic Chemistry, 2010 , vol. 49, # 18 p. 8601 - 8619

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被引用次数: 19

摘要

Lipophilic complexes [Ln (L k)(NO3) 3] with 10 semidendrimeric ligands differing in length, branching, and methyl substitution show nonartifactual enthalpy/entropy compensation for their dimerization in noncoordinating dichloromethane. On the contrary, in the pure complexes, the same structural variations drastically affect the thermotropic liquid-crystalline properties.