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A mild and efficient acetylation of alcohols, phenols and amines with acetic anhydride using La (NO 3) 3· 6H 2 O as a catalyst under solvent-free conditions

TS Reddy, M Narasimhulu, N Suryakiran, KC Mahesh…

文献索引:Reddy, T. Srikanth; Narasimhulu; Suryakiran; Mahesh, K. Chinni; Ashalatha; Venkateswarlu Tetrahedron Letters, 2006 , vol. 47, # 38 p. 6825 - 6829

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被引用次数: 69

摘要

A wide variety of alcohols, phenols and amines are efficiently and selectively converted into the corresponding acetates by treatment with acetic anhydride in the presence of catalytic amounts of La (NO3) 3· 6H2O under solvent-free conditions at room temperature. The method is compatible with acid sensitive hydroxyl protecting groups such as TBDMS, THP, OBz, OBn, Boc and some isopropylidenes and offers excellent yields of the mono acetates ...