Macromolecules

Synthesis and Characterization of Brush-Shaped Hybrid Inorganic/Organic Polymers Based on Polyphosphazenes

X Liu, Z Tian, C Chen, HR Allcock

文献索引：Liu, Xiao; Tian, Zhicheng; Chen, Chen; Allcock, Harry R. Macromolecules, 2012 , vol. 45, # 3 p. 1417 - 1426

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被引用次数: 23

摘要

A series of densely grafted star-and comb-shaped molecular brushes composed of polystyrene, poly (tert-butyl acrylate), and poly (N-isopropylacrylamide) were prepared by atom transfer radical polymerization (ATRP) using either cyclotriphosphazenes or polyphosphazenes as initiators. The initiators were prepared by the introduction of a free hydroxyl group into the side chains of a phosphazene cyclic trimer and polymer, followed ...