Intramolecular addition reactions of functionalized arylcarbenes to double bonds

W Kirmse, G Hoemberger

文献索引：Kirmse, Wolfgang; Hoemberger, Guenter Journal of the American Chemical Society, 1991 , vol. 113, # 10 p. 3925 - 3934

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被引用次数: 31

摘要

Abstract: Arylcarbenes with unsaturated ortho substituents (vinyloxy, 1-propenyloxy, allyl, 2- butenyl, 2, 4-pentadienyl) were generated in methanol by photolysis of diazo precursors. Intermolecular OH insertion was found to compete with intramolecular addition to the ...