Triterpenoid Chemistry. VIII.: Stereospecific Reactions of Triterpenoid 1, 3-Glycol Monotosylates and Ketotosylates

…, K ISOBE, T SANO, A MORIMOTO

文献索引：Tsuda; Isobe; Sano; Morimoto Chemical and Pharmaceutical Bulletin, 1975 , vol. 23, # 1 p. 98 - 105

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被引用次数: 5

摘要

The reactions of 1, 3-glycol monotosylates of the configurations AD with base and LAH were discussed. On reaction with t-butoxide, A and D (cis relationship between-OH and-CH 2 OTs) gave oxetanes E and F respectively, while B and C (trans relationship between these groups) gave the same seco-aldehyde G. On LAH reduction, in addition to the above reaction (oxetane formation from A and D, seco-alcohol formation from B and C), two ...