Aminophosphine ligands R 2 P (CH 2) n NH 2 and ruthenium hydrogenation catalysts RuCl 2 (R 2 P (CH 2) n NH 2) 2

W Jia, X Chen, R Guo, C Sui-Seng, D Amoroso…

文献索引：Jia, Wenli; Chen, Xuanhua; Guo, Rongwei; Sui-Seng, Christine; Amoroso, Dino; Lough, Alan J.; Abdur-Rashid, Kamaluddin Dalton Transactions, 2009 , # 39 p. 8301 - 8307

全文：HTML全文

被引用次数: 15

摘要

The aminophosphine ligands R2P (CH2) 2NH2 and R2P (CH2) 3NH2 (R= Ph, iPr, tBu) were isolated in good to excellent yields from the reaction of LiPR2 with Cl (CH2) 2N (TMS) 2 and Cl (CH2) 3N (TMS) 2, respectively, followed by hydrolysis. This approach allows fine tuning of the ligands' stereoelectronic properties through the variation of the substituents on the phosphine. The aminophosphine ligands were used to prepare the ruthenium complexes ...