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Optically active sulfoxides by enantiospecific reactions of bromovinyl aryl sulfoxides with grignard reagents

C Cardellicchio, V Fiandanese, F Naso, A Scilimati

文献索引：Cardellicchio, Cosimo; Fiandanese, Vito; Naso, Francesco; Scilimati, Antonio Tetrahedron Letters, 1992 , vol. 33, # 35 p. 5121 - 5124

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被引用次数: 29

摘要

Abstract Optically active bromovinyl aryl sulfoxides were subjected to reactions with phenyl- or alkyl-magnesium compounds, with the production of optically active diaryl or aryl alkyl sulfoxides, with inversion of configuration. The enantiospecificity of the process was found to be 98–100%.