First Examples of β??Diketonate Platinum (II) Complexes with Sulfoxide Ligands

SA De Pascali, P Papadia, A Ciccarese…

文献索引：De Pascali, Sandra A.; Papadia, Paride; Ciccarese, Antonella; Pacifico, Concetta; Fanizzi, Francesco P. European Journal of Inorganic Chemistry, 2005 , # 4 p. 788 - 796

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被引用次数: 29

摘要

Abstract New platinum (II) complexes have been prepared as models for explaining the coordination of multiple β-diketonate li-gands to give [Pt (O, O′-acac)(γ-acac) L] species. The new com-pounds containing both an O, O′-chelated acetylacetonate ligand and a sulfoxide in the platinum coordination sphere,[PtCl (O, O′-acac)(DMSO)](1) and [Pt (O, O′- acac)(γ-acac)(DMSO)](2), have been synthesised and characterised by 1 H, 13 C, 195 Pt ...