Tetrahedron letters

Oxidation of dithiocarbamates and synthesis of a stable sulfine

D Chevrie, P Metzner

文献索引：Chevrie, David; Metzner, Patrick Tetrahedron Letters, 1998 , vol. 39, # 49 p. 8983 - 8986

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被引用次数: 17

摘要

Investigation of the oxidation reaction of various dithiocarbamates demonstrated that the corresponding sulfines (S-oxides) are formed. Though their stabilities are very moderate, a number of sulfines could be isolated andv characterised. When left at ambient temperature they decomposed to thiolocarbamates and dithiocarbamates. The sulfines from secondary dithiocarbamates led to disulfides which formation was explained. With a sterically ...