Tetrahedron

Methoxymethylation of tartrate as a strategy for the synthesis of chiral building blocks

H Dulphy, JL Gras, T Lejon

文献索引：Dulphy, Herve; Gras, Jean-Louis; Lejon, Tore Tetrahedron, 1996 , vol. 52, # 25 p. 8517 - 8524

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被引用次数: 23

摘要

Controlled methoxymethylation of tartrate affords mono-and diMOMtartrates. We took advantage of the particular reactivity of methoxymethylethers and of the conformations of the starting C4 unit, to efficiently synthezise various cyclic methyleneketals (dioxane and dioxolane) or cyclic ethers (oxolane and oxetane).