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The Reaction of Ketenes with Grignard Reagents

CD Hurd, RN Jones, FH Blunck

文献索引:Hurd; Jones; Blunck Journal of the American Chemical Society, 1935 , vol. 57, p. 2033,2035

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被引用次数: 6

摘要

Diphenylketen e and phenylmagnesium bromide react'to produce a derivative of triphenylvinyl alcohol. With ketene2 itself, the course of the Grignard reaction has not been established because of the vigor and complexity of the process. Toward the dimer of dimethylketene, ethylmagnesium bromide3 adds to give the cyclic glycol in high yields