Letters in Organic Chemistry

Preparation of Anhydroalditols from Commodity Carbohydrates

C Yuan, RI Hollingsworth

文献索引：Yuan, Changyou; Hollingsworth, Rawle I. Letters in Organic Chemistry, 2013 , vol. 10, # 2 p. 77 - 84

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被引用次数: 1

摘要

A practical process for the preparation of anhydroalditols from commodity carbohydrates has been described. Reductive cleavage of the glycosidic linkage in perallylated carbohydrates with triethylsilane gave the protected anhydroalditols, which were then deallylated using a PdCl2-CuCl2-Activated Charcoal system. Valuable anhydroalditols, such as 1, 5-anhydro-D- glucitol, 1, 5-anhydro-D-mannitol, 2, 5-anhydro-D-glucitol, 2, 5-anhydro-D-mannitol and 1, ...