Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

…, Y Nishibayashi, Y Ishii, Y Mizobe, S Uemura…

文献索引：Takei; Nishibayashi; Ishii; Mizobe; Uemura; Hidai Chemical Communications, 2001 , # 22 p. 2360 - 2361

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被引用次数: 32

摘要

Chiral ruthenium (II) complexes, RuCl2 (PPh3)(oxazolinylferrocenylphosphine), have been found to be effective catalysts for asymmetric hydrosilylation of ketoximes to give the corresponding primary amines in good yields with high enantioselectivities (up to 89% ee) after acid hydrolysis.