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Tetrahedron

The stereodivergent aziridination of allylic carbamates, amides and sulfonamides

…, PM Roberts, AJ Russell, JE Thomson, PA Woods

文献索引:Davies, Stephen G.; Ling, Kenneth B.; Roberts, Paul M.; Russell, Angela J.; Thomson, James E.; Woods, Philip A. Tetrahedron, 2010 , vol. 66, # 34 p. 6806 - 6813

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被引用次数: 15

摘要

A stereodivergent protocol for the aziridination of a range of cyclic allylic amine derivatives has been developed. syn-Products can be obtained in> 99: 1 dr under H-bonded control and anti-products are obtained in> 99: 1 dr under steric control by judicious choice of the N- protecting groups.