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A rationalization of the solvent effect on the Diels–Alder reaction in ionic liquids using multiparameter linear solvation energy relationships

R Bini, C Chiappe, VL Mestre, CS Pomelli…

文献索引:Bini, Riccardo; Chiappe, Cinzia; Mestre, Veronica Llopsis; Pomelli, Christian Silvio; Welton, Thomas Organic and Biomolecular Chemistry, 2008 , vol. 6, # 14 p. 2522 - 2529

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被引用次数: 86

摘要

The Diels–Alder reaction between cyclopentadiene and three dienophiles (acrolein, methyl acrylate and acrylonitrile) having different hydrogen bond acceptor abilities has been carried out in several ionic liquids and molecular solvents in order to obtain information about the factors affecting reactivity and selectivity. The solvent effects on these reactions are examined using multiparameter linear solvation energy relationships. The collected data ...