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Journal of organometallic chemistry

Excimer laser photolysis of tetramethylgermane

J Pola, R Taylor

文献索引:Pola, Josef; Taylor, Roger Journal of Organometallic Chemistry, 1992 , vol. 437, # 3 p. 271 - 278

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被引用次数: 25

摘要

Abstract The ArF laser-induced photolysis of tetramethylgermane (TMG) in the gas-phase yields trimethylgermane, ethane, methane, and ethene, layers of germanium being deposited concomitantly. Trapping experiments with germane-d 4 suggest that major primary steps of the photolysis are molecular extrusions of methane and ethane from TMG.