Synthesis and characterization of a series of monodisperse, 1, 3, 5-phenylene-based hydrocarbon dendrimers including C276H186 and their fluorinated analogs
TM Miller, TX Neenan, R Zayas…
文献索引：Miller, Timothy M.; Neenan, Thomas X.; Zayas, Roberto; Bair, Harvey E. Journal of the American Chemical Society, 1992 , vol. 114, # 3 p. 1018 - 1025
Abstract: The convergent synthesis of a series of monodisperse aromatic dendrimers having molecular diameters of 15-3 1 8, is described. These materials consist of 4, 10, 22, or 46 benzene rings linked symmetrically by u-bonds. Increasingly large dendrimer arms are prepared stepwise via palladium-catalyzed coupling of arylboronic acids to 3, Sdibromo-1- (trimethylsily1) benzene. The aryltrimethylsilane is subsequently converted to a new ...
