Selective hydrodechlorination of fluorinated arylamines

GA Selivanova, LY Gurskaya, LM Pokrovskii…

文献索引：Selivanova, Galina A.; Gurskaya, Larisa Yu.; Pokrovskii, Leonid M.; Kollegov, Vitaliy F.; Shteingarts, Vitaliy D. Journal of Fluorine Chemistry, 2004 , vol. 125, # 12 p. 1829 - 1834

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被引用次数: 14

摘要

Chlorine-containing polyfluorinated anilines and meta-phenylenediamines undergo selective hydrodechlorination easily upon reduction by zinc in aqueous ammonia. A new approach is thus provided to synthetically valuable, partially fluorinated arylamines based on utilizing polyfluorochloroarenes, which are available as intermediates of perfluoroarene production from perchloroarenes. When chlorine atoms are present in positions both ortho ...