Journal of the American Chemical Society

Bis (trimethylstannyl) benzopinacolate-mediated intermolecular free-radical carbon-carbon bond-forming reactions: A new one-carbon homologation

DJ Hart, FL Seely

文献索引：Hart, David J.; Seely, Franklin L. Journal of the American Chemical Society, 1988 , vol. 110, # 5 p. 1631 - 1633

全文：HTML全文

被引用次数: 115

摘要

In an attempt to eliminate reduction of the initially formed radical, we next examined hexamethylditin as a source of stannyl radical^.^^^ Thus, a benzene solution of iodocyclohexane (1. O equiv) and hexamethylditin (1.2 equiv) was irradiated through Pyrex until'H NMR analysis indicated an absence of starting iodide. Product analysis indicated that cyclohexane carboxaldoxime (2) had been generated, presumably via addition of ...