Addition of diphenylphosphine to Michael-type olefins: The preparation of phosphine-nitrile and phosphine-ester ligands

…, RS Button, V Farazi, MK Neeb, CL Tapley…

文献索引：Blinn, D.A.; Button, R.S.; Farazi, V.; Neeb, M.K.; Tapley, C.L.; et al. Journal of Organometallic Chemistry, 1990 , vol. 393, # 1 p. 143 - 152

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被引用次数: 30

摘要

Abstract The reactions of five Michael-type olefins with diphenylphosphine have been carried out. 1-Cyanocyclopentene, 1-cyanocyclohexene, and 4-t-butyl-1-cyanocyclohexene all provide the corresponding 2-diphenylphosphino-1-cyanocycloalkanes, and both methyl acrylate and ethyl methacrylate yield the corresponding 2-diphenylphosphinopropionates. For the products from 1-cyanocyclopentene and 1-cyanocyclohexene, 13 C and 31 P ...