Controlled free radical polymerization in water-borne dispersion using reversible addition-fragmentation chain transfer

…, D De Wet-Roos, MP Tonge, RD Sanderson

文献索引：Vosloo; De Wet-Roos; Tonge; Sanderson Macromolecules, 2002 , vol. 35, # 13 p. 4894 - 4902

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被引用次数: 116

摘要

A novel approach to conducting controlled free radical polymerization in water-borne organic dispersions using reversible addition-fragmentation chain transfer (RAFT) has been studied. The novel approach in this study focused on eliminating monomer and oligomer transport and comprised two fundamental steps: the synthesis of dithiobenzoate-end- capped styrene oligomers in bulk followed by emulsification of these oligomers to yield a ...