Journal of the American Chemical Society

Cleavage of carbon-carbon bonds of diphenylacetylene and its derivatives via photolysis of pt complexes: Tuning the cc bond formation energy toward selective cc …

A Gunay, WD Jones

文献索引：Gunay, Ahmet; Jones, William D. Journal of the American Chemical Society, 2007 , vol. 129, # 28 p. 8729 - 8735

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被引用次数: 48

摘要

Carbon-carbon bond activation of diphenylacetylene and several substituted derivatives has been achieved via photolysis and studied. Pt0-acetylene complexes with η2-coordination of the alkyne, along with the corresponding PtII CC activated photolysis products, have been synthesized and characterized, including X-ray crystal structural analysis. While the CC cleavage reaction occurs readily under photochemical conditions, thermal activation of the ...