Bulletin of the Chemical Society of Japan

Polymer reagents derived from sodium p-styrenesulfonate: N-methyl-N-nitroso-p-styrenesulfonamide and p-styrenesulfinic acid polymers.

H Kamogawa, T Kitamura

文献索引：Kamogawa, Hiroyoshi; Kitamura, Tomoo Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 1 p. 189 - 192

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被引用次数: 5

摘要

N-Methyl-N-nitroso-p-styrenesulfonamide (1) was synthesized starting with sodium p- styrenesulfonate (3). Monomer 1 and sodium p-styrenesulfinate (2), also synthesized starting with 3, were polymerized and polymer of 2 was converted to corresponding free acid (9). The function of polymer of 1 as the reagent attaching the CH 2 group to the carbonyl carbon by insertion and that of polymer 9 as the catalyst for cis→ trans isomerization were ...