Chemoselective hydrogenation of α, β-unsaturated aldehydes with modified Pd/C catalyst
…, ZM Rong, Y Liang, Y Wang, XY Lu, YF Wang…
文献索引:Du, Wen Qiang; Rong, Ze Ming; Liang, Yan; Wang, Yong; Lu, Xin Yi; Wang, Yi Fan; Lu, Lian Hai Chinese Chemical Letters, 2012 , vol. 23, # 7 p. 773 - 776
Selective hydrogenation of α, β-unsaturated aldehydes with modified Pd/C catalyst was developed. The reduction of CO bond could be efficiently inhibited by the addition of carbonates, and high selectivity to the corresponding saturated aldehydes was achieved under mild conditions. This protocol provides an alternative for efficient preparation of saturated aldehydes.