Metalloporphyrin-catalyzed aerobic oxidation of 2-methoxy-4-methylphenol as a route to vanillin

Q Jiang, W Sheng, X Guo, J Tang, C Guo

文献索引：Jiang, Qing; Sheng, Wenbing; Guo, Xiangdong; Tang, Jie; Guo, Cancheng Journal of Molecular Catalysis A: Chemical, 2013 , vol. 373, p. 121 - 126

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被引用次数: 6

摘要

We report the use of simple metalloporphyrins (T (p-Cl) PPMnCl, T (p-Cl) PPCo, T (p-Cl) PPFeCl, T (p-Cl) PPCu or [T (p-Cl) PPFe] 2O) as a catalyst for the direct oxidation of 2- methoxy-4-methylphenol to vanillin with molecular oxygen under mild conditions. The research results showed that the type of metalloporphyrin used, catalyst loading, temperature, reaction time, the amount of NaOH, solvent, the amount of solvent and the ...