Canadian Journal of Chemistry

Regioselectivity in cycloaddition reactions on solid phases

V Yedidia, CC Leznoff

文献索引：Yedidia, Varda; Leznoff, Clifford C. Canadian Journal of Chemistry, 1980 , vol. 58, p. 1144 - 1150

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被引用次数: 71

摘要

A 1% crosslinked divinylbenzene-styrene copolymer, incorporating benzyl acrylate groups, reacted in normal Diels-Alder reactions with E-1-phenyl-1, 3-butadiene or methyl E-2, 4- pentadienoate to give their respective polymer-bound benzyl cyclohexenecarboxylates. Polymer-bound benzyl propiolate and polymer-bound benzyl phenylpropiolate reacted with benzonitrile oxide in a typical 1, 3-dipolar addition reaction to give their respective ...