Some Synthetic Interconversions in the Nitrocyclohexane System

HH Baer, DC Shields…

文献索引：Baer,H.H. et al. Canadian Journal of Chemistry, 1973 , vol. 51, p. 2843 - 2852

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被引用次数: 5

摘要

Several transformations starting from trans, trans-2-nitrocyclohexane-1, 3-diol (1) and its diacetate (2) were carried out as model reactions for synthetic work on nitro sugars. They included methylation with diazomethane, dehydration, dehydroacetylation, nucleophilic elimination-additions with alcohols, and bromination. The monomethyl ether of 1 (3), the monomethyl ether acetate (5), the dimethyl and dibenzyl ethers (4 and 9), bromonitro ...