Carbonylation of mixed trialkylboranes containing substituents as a synthetic route to unsymmetrical ketones with such functional substituents. Route for the …

HC Brown, GW Kabalka…

文献索引：Brown,H.C. et al. Journal of the American Chemical Society, 1967 , vol. 89, p. 4530 - 4531

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被引用次数: 14

摘要

(1967); MW Rathke and HC Brouii, ibrd.. 89. L710 (1967). cyclohexyl ketone. When the same reaction is carried out in tetrahydrofuran at 45", the total yield of ketone was 86z, composed of 92% cyclohexyl n-octyl ketone and only 8 dicyclohexyl ketone. We applied this reaction to methyl 10-undecenoate, 10-undecenyl benzoate, allyl benzoate, ethyl vinylacetate, and allyl cyanide. We encountered difficulties in attempting to put some of ...