Acid-catalyzed rearrangement of the exo-1, 2-dioxetane derivative from 1-isopropylidene-4, 4-diphenyl-2, 5-cyclohexadiene.

A Kawamoto, H Uda, N Harada

文献索引：Kawamoto, Akira; Uda, Hisashi; Harada, Nobuyuki Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 11 p. 3279 - 3283

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被引用次数: 11

摘要

It is shown that acid-catalyzed decomposition of the 1, 2-dioxetane derivative, 3, 3-dimethyl- 7, 7-diphenyl-1-2-dioxaspiro [3.5] nona-5, 8-diene, obtained from 1-isopropylidene-4, 4- diphenyl-2, 5-cyclohexadiene, gives 1-methyl-1-(o-terphenyl-4′-yl) ethyl hydroperoxide, bis [1-methyl-1-(o-terphenyl-4′-yl) ethyl] peroxide, 1-(1-hydroperoxy-1-methylethyl)-4, 4- diphenylcyclohexa-2, 5-dien-1-ol, and o-terphenyl-4′-ol, along with the usual dioxetane- ...