Chemistry of organo halogenic molecules. Part 100. Comparative behaviour of xenon diflouride and caesium fluoroxysulphate in the fluorination of enol acetates and …
S Stavber, B Šket, B Zajc, M Zupan
文献索引：Stavber, Stojan; Sket, Boris; Zajc, Barbara; Zupan, Marko Tetrahedron, 1989 , vol. 45, # 18 p. 6003 - 6010
Xenon difluoride and caesium fluoroxysulphate reacted in methylene chloride or acetonitrile with various enol acetates, diketones, and ketones, yielding mainly α-fluoro ketones, the course of the reaction depending on the reagent and the structure of the organic molecule. Enol acetates from cycloakanones were converted with caesium fluoroxysulphate to α- fluorocycloalkanones in high yield. Xenon difluoride and caesium fluoroxysulphate ...
