Intramolecular alkylation of of α, β-unsaturated ketones: a study of the effect of substrate structure and experimental conditions on the site of alkylation
E Piers, M Zbozny, DC Wigfield
文献索引：Piers,E. et al. Canadian Journal of Chemistry, 1979 , vol. 57, p. 1064 - 1074
The syntheses of 4a-(3-chloropropyl)-(22), 4a-(3-iodopropyl)-(23), and 4a-mesyloxymethyl- 4, 4a, 5, 6, 7, 8-hexahydro-2 (3 H)-naphthalenone (24) are described. The results obtained from the intramolecular alkylation of each of these compounds under a variety of experimental conditions are summarized in Tables 1 and 2. It was found that alkylative cyclization of compounds 22 and 23 gave varying amounts of two products, one (34) ...
