Metalation of phenols. Synthesis of benzoquinones by the oxidative degradation approach

…, A Llobera, A Garcia-Raso, A Costa…

文献索引：Saa, Jose M.; Llobera, Antonia; Garcia-Raso, Angel; Costa, Antonio; Deya, Pedro M. Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4263 - 4273

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被引用次数: 27

摘要

In an effort to explore the potential of the so-called oxidative degradation approach for the synthesis of quinones, we have investigated the direct metalation of a number of simple phenols such as o-and p-hydroxybenzyl alcohols, benzyl methyl ethers and Nfl- dimethylbenzylamines. Apparently, only those phenolic substrates having available both a coordinating group for chelation and an electron-withdrawing group in a 1, 3-relationship ...