Iridium??Catalyzed Highly Enantioselective Hydrogenation of Exocyclic α, β??Unsaturated Carbonyl Compounds

…, D Yao, Y Liu, F Xie, W Zhang

文献索引：Tian, Fengtao; Yao, Dongmei; Liu, Yuanyuan; Xie, Fang; Zhang, Wanbin Advanced Synthesis and Catalysis, 2010 , vol. 352, # 11-12 p. 1841 - 1845

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被引用次数: 31

摘要

Abstract By using the iridium complex of a phosphine-oxazoline ligand with an axis-unfixed biphenyl backbone, a highly enantioselective hydrogenation of the C [DOUBLE BOND] C bond of exocyclic α, β-unsaturated carbonyl compounds to afford α-chiral cyclic ketones, lactones and lactams was developed.