Bipolar molecules with high triplet energies: Synthesis, photophysical, and structural properties

Y Zheng, AS Batsanov, V Jankus, FB Dias…

文献索引：Zheng, Yonghao; Batsanov, Andrei S.; Jankus, Vygintas; Dias, Fernando B.; Bryce, Martin R.; Monkman, Andrew P. Journal of Organic Chemistry, 2011 , vol. 76, # 20 p. 8300 - 8310

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被引用次数: 39

摘要

This article sheds new light on the interplay of electronic and conformational effects in luminescent bipolar molecules. A series of carbazole/1, 3, 4-oxadiazole hybrid molecules is described in which the optoelectronic properties are systematically varied by substituent effects which tune the intramolecular torsion angles. The synthesis, photophysical properties, cyclic voltammetric data, X-ray crystal structures, and DFT calculations are ...