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The Journal of Organic Chemistry

Free Radical Rearrangements in the Decarbonylation of Aldehydes1

DY CURTIN, JC KAUER

文献索引:Curtin,D.Y.; Kauer,J.C. Journal of Organic Chemistry, 1960 , vol. 25, p. 880 - 885

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被引用次数: 24

摘要

The reaction of p-deutero-P-(p-anisyl)-j3-phenylpropionaldehyde with di-t-butyl peroxide has been found to give decarbonylation without rearrangement of the deuterium atom.* 4 reinvestigation of the decarbonylation of p, &j3-triphenylpropionaldehyde has shown that in addition to the 1, 1, 2-triphenylethane previously reported there are present lesser amounts of triphenylethylene and 3, 3-diphenyl-l-indanone. Decarbonylation of j3-(pnitrophenyl)-P, ...