Tetrahedron

Catalytic C–C bond formation promoted by Mg–Al–O–t-Bu hydrotalcite

BM Choudary, ML Kantam, B Kavita, CV Reddy…

文献索引：Choudary; Lakshmi Kantam; Kavita; Venkat Reddy; Figueras Tetrahedron, 2000 , vol. 56, # 47 p. 9357 - 9364

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被引用次数: 101

摘要

Mg–Al–O–t-Bu-hydrotalcite catalyst was found to be an efficient, environmentally attractive and selective solid base catalyst for 1, 4 Michael addition. Mg–Al–O–t-Bu hydrotalcite is also effective for simple synthesis of α, β-unsaturated esters and nitriles by condensation of the corresponding activated carboxylic esters or nitriles with various aldehydes by Knoevenagel condensation. These reactions proceeded at room temperature at a greater rate in the ...