Advanced Synthesis & Catalysis

Copper??Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading

RD Patil, S Adimurthy

文献索引：Patil, Rajendra D.; Adimurthy, Subbarayappa Advanced Synthesis and Catalysis, 2011 , vol. 353, # 10 p. 1695 - 1700

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被引用次数: 103

摘要

Abstract The copper (I)-catalyzed direct synthesis of imines from amines under mild aerobic conditions is described. The method is applicable for the synthesis of various imines from corresponding amines such as benzylic, aliphatic, cyclic secondary, heteroaromatic species and the oxidative condensation of benzylamines with anilines extends the scope of the CuCl catalytic system. Noteworthy, solvent-free procedure, air as a benign oxidant, and the ...