Journal of Molecular Catalysis A: Chemical

Preparation of tethered half-titanocene complex on cross-linked polystyrene beads for using in syndiospecific polymerization of styrene

S Rahmani, AA Entezami

文献索引：Rahmani, Sohrab; Entezami Journal of Molecular Catalysis A: Chemical, 2010 , vol. 320, # 1-2 p. 27 - 33

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被引用次数: 6

摘要

In this work the cross-linked polystyrene beads were functionalized with silyl hydride groups. Two synthetic procedures were employed to tether of indenyltrichlorotitanium (IndTiCl3) on the functionalized polystyrene beads. In one approach (method A), the half-titanocene catalyst bearing an allyl group (1-allylindenyltrichlorotitanium) was synthesized and covalently anchored on the functionalized polystyrene by using of hydrosilylation ...