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The Thermal Rearrangement of Triarylmethyl Azides1

WH Saunders Jr, JC Ware

文献索引:Saunders; Ware Journal of the American Chemical Society, 1958 , vol. 80, p. 3328,3331

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被引用次数: 47

摘要

A series of triarylxnetliyl azides of the type pX-CsI11 (Ce€ I~) 2C~ i3, where X= 13, CI-I, O, CH,, C1, NO2 and N (CHJ2, has been prepared. On heating to 170-190" these substances evolve nitrogen to give mixtures of benzophenone anils. Analyses of the benzophenones from hydrolysis of the anils were used to determine migration aptitudes of the aryl groups. These migration aptitudes are relatively insensitive to the nature of the aryl group--p-anisyl ...