The Journal of Organic Chemistry

A one-pot conversion of olefins to. alpha.,. beta.-unsaturated carbonyl compounds. An easy synthesis of 2-cyclopentenone and related compounds

ED Mihelich, DJ Eickhoff

文献索引：Mihelich, Edward D.; Eickhoff, David J. Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4135 - 4137

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被引用次数: 112

摘要

There are few compounds that have more potential and versatility in organic synthesis than 2-cyclopentenone'and its higher homologues. Yet the available sources of these materials are generally tedious, multistep synthetic routes2 or expensive commercial supplier^.^ A conceptually attractive synthetic entry to this general class of compounds lies in the direct conversion of their parent olefins4 through an allylic oxidation pathway. While an ...