Organic letters

Palladium-catalyzed chloroimination of imidoyl chlorides to a triple bond: an intramolecular reaction leading to 4-chloroquinolines

A Isobe, J Takagi, T Katagiri, K Uneyama

文献索引：Isobe, Akira; Takagi, Jun; Katagiri, Toshimasa; Uneyama, Kenji Organic Letters, 2008 , vol. 10, # 13 p. 2657 - 2659

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被引用次数: 41

摘要

In this paper, a new type of effective chloroimination was reported. This reaction afforded 4- chloro-2-perfluoroalkyl quinolines from fluorinated imidoyl chlorides in high yields. This is the first achievement of oxidative addition− reductive elimination type C− Cl bond activation by chloropalladation.