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Tetrahedron

The search for new biochemical photoprobes. II. The nucleophilic photosubstitution of 2-fluoro-4-nitroanisole.

R Pleixats, M Figueredo, J Marquet, M Moreno-Mañas…

文献索引:Pleixats, R.; Figueredo, M.; Marquet, J.; Moreno-Manas, M.; Cantos, A. Tetrahedron, 1989 , vol. 45, # 24 p. 7817 - 7826

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被引用次数: 9

摘要

The photosubstitutions of 2-fluoro-4-nitroanisole with several amines are studied. The preparative results, the thermal stability of the photochemical substrate, and the limiting quantum yield values obtained from photoreactions with several nucleophiles suggest the possible usefulness of 2-fluoro-4-nitrophenyl ethers as biochemical photoprobes.