Journal of Molecular Structure

Synthesis and characterization of benzimidazole-based zinc complexes as structural carbonic anhydrase models and their applications towards CO 2 hydration

MM Ibrahim, MA Amin, K Ichikawa

文献索引：Ibrahim, Mohamed M.; Amin, Mahmoud A.; Ichikawa, Kazuhiko Journal of Molecular Structure, 2011 , vol. 985, # 2-3 p. 191 - 201

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被引用次数: 12

摘要

The tripod ligand tris (2-benzimidazolylmethyl) amine L1 and its methylated derivative tris (N- methyl-2-benzimidazolylmethyl) amine L2 were used for the preparation of chloro complexes [L1Zn–Cl](PF6) 1 and [L2Zn–Cl](PF6) 2. These complexes reacted with AgPF6 in aqueous acetone to form the corresponding aqua complexes [L1Zn–OH2](PF6) 23,[L2Zn (H2O)](PF6) 24, which were deprotonated by using KOH to form the hydroxide complexes ...