Tetrahedron

1, 2, 3-Triazol-5-ylidene–palladium complex catalyzed Mizoroki–Heck and Sonogashira coupling reactions

…, H Hiroki, T Terashima, K Ogata, S Fukuzawa

文献索引：Inomata, Sayuri; Hiroki, Hidekatsu; Terashima, Takahiro; Ogata, Kenichi; Fukuzawa, Shin-Ichi Tetrahedron, 2011 , vol. 67, # 38 p. 7263 - 7267

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被引用次数: 38

摘要

The bis-1, 4-dimesityl-1, 2, 3-triazol-5-ylidene–palladium complex (1a) successfully catalyzes the Mizoroki–Heck and Sonogashira coupling reactions with aryl bromides to give the corresponding alkenes and alkynes, respectively, in good to excellent yields. In the Mizoroki–Heck reaction, electron-rich, electron-poor, and functionalized aryl bromides and alkenes are tolerated, while the substrates are limited to electron-poor aryl halides in the ...