Silver (I) ion catalyzed rearrangements of strained. sigma. bonds. XXIX. Influence of structural features on the course of transition metal catalyzed 1, 8-bishomocubane …

LA Paquette, RA Boggs, WB Farnham…

文献索引：Paquette,L.A. et al. Journal of the American Chemical Society, 1975 , vol. 97, # 5 p. 1112 - 1118

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被引用次数: 10

摘要

Abstract: Evidence is presented that the rearrangements of several I, 8-bishomocubane derivatives by various Rh (1) and Pd (ll) catalysts are sensitive not only to the nature of the ligands attached to the metal but also to the level of substitution at the reaction site (C, and CS). Thus, the level of snoutane production increases in the order [Rh (NOR) C1] 2< Pdlz (PPh&< PdCIZ (PPh3) z< PdCI>(PhCN) 2 irrespective of the degree or nature of the ...