A modular approach toward regulating the secondary coordination sphere of metal ions: differential dioxygen activation assisted by intramolecular hydrogen …

RL Lucas, MK Zart, J Murkerjee, TN Sorrell…

文献索引：Lucas, Robie L.; Zart, Matthew K.; Murkerjee, Jhumpa; Sorrell, Thomas N.; Powell, Douglas R.; Borovik Journal of the American Chemical Society, 2006 , vol. 128, # 48 p. 15476 - 15489

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被引用次数: 57

摘要

Metal ion function depends on the regulation of properties within the primary and second coordination spheres. An approach toward studying the structure-function relationships within the secondary coordination sphere is to construct a series of synthetic complexes having constant primary spheres but structurally tunable secondary spheres. This was accomplished through the development of hybrid urea-carboxamide ligands that provide ...