Nickel (II)??Magnesium??Catalyzed Cross??Coupling of 1, 1??Dibromo??1??alkenes with Diphenylphosphine Oxide: One??Pot Synthesis of (E)??1??Alkenylphosphine Oxides …

L Liu, Y Wang, Z Zeng, P Xu, Y Gao…

文献索引：Liu, Liu; Wang, Yulei; Zeng, Zhiping; Xu, Pengxiang; Gao, Yuxing; Yin, Yingwu; Zhao, Yufen Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 659 - 666

全文：HTML全文

被引用次数: 28

摘要

Abstract A novel nickel (II)-magnesium-mediated cross-coupling of diphenylphosphine oxide with a variety of 1, 1-dibromo-1-alkenes has been developed, which provides a powerful and general methodology for the stereoselective synthesis of various (E)-1- alkenylphosphine oxides or bisphosphine oxides, with operational simplicity of the procedure, good to high yields and broad substrate applicability. Mechanistic studies ...