Titanium (III) Chloride Mediated Reduction of Dicyanoalkenes.

A Sera, T Tsuzuki, E Satoh, K Itoh

文献索引：Sera, Akira; Tsuzuki, Toshihiro; Satoh, Eishi; Itoh, Kuniaki Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 3068 - 3071

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被引用次数: 7

摘要

The reaction of substituted dicyanoalkenes with aqueous titanium (III) chloride was examined. The dicyanoalkenes, which showed irreversible reduction characteristics on cyclic voltammograms,(typically, 2-cyano-3-phenylpropenenitrile), afforded cyclized and/or uncyclized hydrodimers, while those characterized by reversible reduction behavior,(typically, 2-cyano-3, 3-diphenylpropenenitrile), yielded the corresponding ...