Glycol ester formation in the Reformatskii reaction

…, E Gawronska, KL Rinehart

文献索引：Plattner, Jacob J.; Gawronska, Eva; Rinehart, Kenneth L. Journal of Organic Chemistry, 1982 , vol. 47, # 18 p. 3440 - 3442

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被引用次数: 1

摘要

A previously unrecognized side reaction in the Reformatsky reaction has been identified in the reaction of heptanal with ethyl bromoacetate. The products are derived from the two isomeric heptanoates of the glycol 2-pentyl-3-hydroxynonano1, formed from 3 mol of heptanal under the presumed catalysis of the bromo zinc enolate.