Abstract 1, 3-Dipolar cycloadditions were carried out with 1, 2, 3-triazinium 2- dicyanomethylylides 4 and deprotonated 2-ethyl-1, 2, 3-triazinium salts 2. Pyrazolo [2, 1-a]- and pyrazolo [1, 2-b][1, 2, 3] triazines 5 and 9 were synthesized, representing new